| Literature DB >> 23421716 |
Hiroumi Mitome1, Tomoya Ishizuka, Yoshihiko Shiota, Kazunari Yoshizawa, Takahiko Kojima.
Abstract
Herein, we report the synthesis of a novel heterohexanuclear complex (1) of a heteroaromatic cofactor, pyrroloquinolinequinone (PQQ). The crystal structure of 1 was determined to reveal that two PQQ-bridged Ru(II)Ag(I) units were linked by two [Ag(I)(OTf)2](-) units (OTf = CF3SO3(-)). A solvent-bound Ru(II)Ag(I) heterodinuclear complex (2) was formed from 1 in a coordinating solvent such as acetone to show an intense metal-to-ligand charge-transfer band at 709 nm.Entities:
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Year: 2013 PMID： 23421716 DOI： 10.1021/ic302617b
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165