Literature DB >> 23418777

Novel hexanuclear copper(II) complex built from a simple tetrachelating triazole ligand: synthesis, structure, and magnetism.

J Hernández-Gil1, N Ovèjak, S Ferrer, F Lloret, A Castiñeiras.   

Abstract

A new easy symmetric 3,5-disubstituted 1,2,4-triazole ligand (H3diV) by reaction with an excess of copper(II) salt has afforded a novel hexanuclear compound (Cu/HdiV ratio of 6:2) through a bis(trans-cis-cis-trans) binding mode, exhibiting two types of Cu(II) centers and two clearly distinguishable antiferromagnetic J1 (-234 cm(-1)) and J2 (-35 cm(-1)) coupling constants.

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Year:  2013        PMID: 23418777     DOI: 10.1021/ic3027946

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  2 in total

1.  Hexanuclear Cu3O-3Cu triazole-based units as novel core motifs for high nuclearity copper(ii) frameworks.

Authors:  Sacramento Ferrer; Javier Hernández-Gil; Francisco Javier Valverde-Muñoz; Francisco Lloret; Alfonso Castiñeiras
Journal:  RSC Adv       Date:  2019-09-17       Impact factor: 4.036

2.  Study of Chemical Intermediates by Means of ATR-IR Spectroscopy and Hybrid Hard- and Soft-Modelling Multivariate Curve Resolution-Alternating Least Squares.

Authors:  Junxiu Ma; Juan Qi; Xinyu Gao; Chunhua Yan; Tianlong Zhang; Hongsheng Tang; Hua Li
Journal:  J Anal Methods Chem       Date:  2017-03-12       Impact factor: 2.193

  2 in total

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