| Literature DB >> 23416542 |
Florian Dulong1, Jacky Pouessel, Pierre Thuéry, Jean-Claude Berthet, Michel Ephritikhine, Thibault Cantat.
Abstract
The first examples of inorganic nitrite complexes of the natural actinides are described, including the structures of the homoleptic thorium(IV) [PPh(4)](2)[Th(NO(2))(6)] and the uranyl(VI) [PPh(4)](2)[UO(2)(NO(2))(4)] complexes; the nitrite ligand can adopt two different coordination modes in the coordination sphere of the uranyl ion and is unstable towards reduction.Entities:
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Year: 2013 PMID： 23416542 DOI： 10.1039/c3cc39163a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222