| Literature DB >> 23406020 |
Soham Maity1, Srimanta Manna, Sujoy Rana, Togati Naveen, Arijit Mallick, Debabrata Maiti.
Abstract
Nitroolefin is a common and versatile reagent. Its synthesis from olefin is generally limited by the formation of mixture of cis and trans compounds. Here we report that silver nitrite (AgNO2) along with TEMPO can promote the regio- and stereoselective nitration of a broad range of olefins. This work discloses a new and efficient approach wherein starting from olefin, nitroalkane radical formation and subsequent transformations lead to the desired nitroolefin in a stereoselective manner.Entities:
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Year: 2013 PMID： 23406020 DOI： 10.1021/ja311942e
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419