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Literature DB >> 23404960

A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl.

Lani A Seaman¹, Peter Hrobárik, Michael F Schettini, Skye Fortier, Martin Kaupp, Trevor W Hayton.

Abstract

Entities: Chemical

Year: 2013 PMID： 23404960 DOI： 10.1002/anie.201209611

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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2 in total

1. Use of ¹⁵N NMR spectroscopy to probe covalency in a thorium nitride.

Authors: Selena L Staun; Dumitru-Claudiu Sergentu; Guang Wu; Jochen Autschbach; Trevor W Hayton
Journal: Chem Sci Date: 2019-06-04 Impact factor: 9.825

2. Isolation and characterization of a covalent Ce^IV-Aryl complex with an anomalous ¹³C chemical shift.

Authors: Grace B Panetti; Dumitru-Claudiu Sergentu; Michael R Gau; Patrick J Carroll; Jochen Autschbach; Patrick J Walsh; Eric J Schelter
Journal: Nat Commun Date: 2021-03-17 Impact factor: 14.919

2 in total

A rare uranyl(VI)-alkyl ate complex [Li(DME)1.5]2[UO2(CH2SiMe3)4] and its comparison with a homoleptic uranium(VI)-hexaalkyl.

1. Use of 15N NMR spectroscopy to probe covalency in a thorium nitride.

2. Isolation and characterization of a covalent CeIV-Aryl complex with an anomalous 13C chemical shift.

1. Use of ¹⁵N NMR spectroscopy to probe covalency in a thorium nitride.

2. Isolation and characterization of a covalent Ce^IV-Aryl complex with an anomalous ¹³C chemical shift.