Literature DB >> 23403976

Reversible structural transformation and selective gas adsorption in a unique aqua-bridged Mn(II) metal-organic framework.

Euna Jeong1, Woo Ram Lee, Dae Won Ryu, Yeonga Kim, Won Ju Phang, Eui Kwan Koh, Chang Seop Hong.   

Abstract

An aqua-bridged Mn metal-organic framework was prepared, and a dramatic structural transformation occurs upon solvent exchange-resolvation and desolvation-resolvation processes. The desolvated phase, formed by removing the aqua bridges, exhibits selective CO(2) uptake over N(2), H(2), and CH(4). Further, antiferromagnetic couplings are also found between Mn spins in the secondary building units.

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Year:  2013        PMID: 23403976     DOI: 10.1039/c3cc00093a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  A green strategy to prepare metal oxide superstructure from metal-organic frameworks.

Authors:  Yonghai Song; Xia Li; Changting Wei; Jinying Fu; Fugang Xu; Hongliang Tan; Juan Tang; Li Wang
Journal:  Sci Rep       Date:  2015-02-11       Impact factor: 4.379

2.  2D MOF Nanoflake-Assembled Spherical Microstructures for Enhanced Supercapacitor and Electrocatalysis Performances.

Authors:  Huicong Xia; Jianan Zhang; Zhao Yang; Shiyu Guo; Shihui Guo; Qun Xu
Journal:  Nanomicro Lett       Date:  2017-03-28
  2 in total

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