| Literature DB >> 23403900 |
Frederic Poineau1, Philippe F Weck, Benjamin P Burton-Pye, Ibthihel Denden, Eunja Kim, William Kerlin, Konstantin E German, Massoud Fattahi, Lynn C Francesconi, Alfred P Sattelberger, Kenneth R Czerwinski.
Abstract
The reaction between HTcO(4) and MeOH in 13 M H(2)SO(4) was investigated by (99)Tc NMR, UV-visible and X-ray absorption fine structure (XAFS) spectroscopy. Experimental results and first principles calculations show the formation of Tc(+5) sulfate complexes. The results expand the fundamental understanding of Tc in high acid solutions.Entities:
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Year: 2013 PMID： 23403900 DOI： 10.1039/c3dt32951h
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390