Literature DB >> 23401124

The synthesis of hexafluorosumanene and its congeners.

Bernd M Schmidt1, Berit Topolinski, Shuhei Higashibayashi, Tatsuhiro Kojima, Masaki Kawano, Dieter Lentz, Hidehiro Sakurai.   

Abstract

Bowled over: A family of gem-difluorinated sumanenes was synthesised, including the highly symmetric hexafluorosumanene (see figure). The favourable columnar structure is maintained upon fluorination. Substitution by electron-withdrawing substituents increases the bowl depth and results in a large cathodic shift of the reduction potential.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2013        PMID： 23401124     DOI： 10.1002/chem.201204622

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  4 in total

1.  (19)F NMR-, ESR-, and vis-NIR-spectroelectrochemical study of the unconventional reduction behaviour of a perfluoroalkylated fullerene: dimerization of the C70(CF3)10(-) radical anion.

Authors:  Michal Zalibera; Peter Machata; Tyler T Clikeman; Marco Rosenkranz; Steven H Strauss; Olga V Boltalina; Alexey A Popov
Journal:  Analyst       Date:  2015-11-07       Impact factor: 4.616

2.  1-[(Anthracen-9-yl)carbon-yl]-2,7-di-meth-oxy-naphthalene: a chain-like structure composed of face-to-face type dimeric mol-ecular aggregates.

Authors:  Takehiro Tsumuki; Kazuki Ogata; Noriyuki Yonezawa; Akiko Okamoto
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-11-18

3.  Columnar/herringbone dual crystal packing of pyrenylsumanene and its photophysical properties.

Authors:  Binod Babu Shrestha; Shuhei Higashibayashi; Hidehiro Sakurai
Journal:  Beilstein J Org Chem       Date:  2014-04-11       Impact factor: 2.883

4.  Hexathioalkyl sumanenes: an electron-donating buckybowl as a building block for supramolecular materials.

Authors:  Yoshiaki Shoji; Takashi Kajitani; Fumitaka Ishiwari; Qiang Ding; Hiroyasu Sato; Hayato Anetai; Tomoyuki Akutagawa; Hidehiro Sakurai; Takanori Fukushima
Journal:  Chem Sci       Date:  2017-10-18       Impact factor: 9.825
  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.