| Literature DB >> 23385547 |
Tianshu Li1, Michael T Gamer, Manfred Scheer, Sergey N Konchenko, Peter W Roesky.
Abstract
The two new 3d/4f polyphosphide complexes [(Cp*Fe)(2)P(10){Sm(η(5)-C(5)Me(4)R)(2)}(2)] (Cp* = η(5)-C(5)Me(5); R = Me, nPr) were prepared by reductive dimerization of [Cp*Fe(η(5)-P(5))] with samarocenes. They are the first P(10) bridging 3d/4f metal complexes and the first examples of reductive coupling of polyphosphide complexes by divalent lanthanides.Entities:
Mesh：
Substances：
Year: 2013 PMID： 23385547 DOI： 10.1039/c3cc38841g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222