Literature DB >> 23376901

Thiourea-catalyzed aminolysis of N-acyl homoserine lactones.

Michael A Bertucci1, Stephen J Lee, Michel R Gagné.   

Abstract

Thiourea catalysts accelerate aminolysis of N-acyl homoserine lactones (AHLs), molecules integral to bacterial quorum sensing. The catalysts afford rate enhancement of up to 10 times the control in CD(3)CN. Mild catalysis in other polar aprotic solvents is still observed, while the activity is attenuated in polar protic solvents.

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Year:  2013        PMID: 23376901     DOI: 10.1039/c3cc00268c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Rate Accelerated Organocatalytic Ring-Opening Polymerization of L-Lactide via the Application of a Bis(thiourea) H-bond Donating Cocatalyst.

Authors:  Samuel S Spink; Oleg I Kazakov; Elizabeth T Kiesewetter; Matthew K Kiesewetter
Journal:  Macromolecules       Date:  2015-08-20       Impact factor: 5.985

2.  Specific Affinity Enrichment of Electrochemically Cleaved Peptides Based on Cu(II)-Mediated Spirolactone Tagging.

Authors:  Tao Zhang; Marcel P de Vries; Hjalmar P Permentier; Rainer Bischoff
Journal:  Anal Chem       Date:  2017-06-19       Impact factor: 6.986

3.  A high throughput screening method for the nano-crystallization of salts of organic cations.

Authors:  Philipp P Nievergelt; Martin Babor; Jan Čejka; Bernhard Spingler
Journal:  Chem Sci       Date:  2018-03-12       Impact factor: 9.825

  3 in total

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