| Literature DB >> 23368906 |
Vitalij V Levin1, Artem A Zemtsov, Marina I Struchkova, Alexander D Dilman.
Abstract
Reactions of difluorocarbene with benzyl and alkylzinc halides leading to fluorinated organozinc species have been described. The generated α-difluorinated organozinc reagents are reasonably stable in solution and can be quenched with external electrophiles (iodine, bromine, proton), affording compounds containing the CF(2) fragment.Entities:
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Year: 2013 PMID： 23368906 DOI： 10.1021/ol400122k
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005