Literature DB >> 23362133

An organosilicon cluster with an octasilacuneane core: a missing silicon cage motif.

Shintaro Ishida1, Kyohei Otsuka, Yuki Toma, Soichiro Kyushin.   

Abstract

Cagey silicon: A silicon cluster, consisting of sixteen silicon atoms and composed of an octasilacuneane core (red, see picture) fused with cyclotetrasilanes (orange), was synthesized by reductive tetramerization of tetrachlorocyclotetrasilane. Analytical and theoretical studies reveal the unique structural and electronic features of this organosilicon cluster.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2013        PMID： 23362133     DOI： 10.1002/anie.201208506

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  A highly unsaturated six-vertex amido-substituted silicon cluster.

Authors:  Jan Keuter; Christian Schwermann; Alexander Hepp; Klaus Bergander; Jörn Droste; Michael Ryan Hansen; Nikos L Doltsinis; Christian Mück-Lichtenfeld; Felicitas Lips
Journal:  Chem Sci       Date:  2020-05-11       Impact factor: 9.825

2.  Atomically Precise Expansion of Unsaturated Silicon Clusters.

Authors:  Kinga I Leszczyńska; Volker Huch; Carsten Präsang; Jan Schwabedissen; Raphael J F Berger; David Scheschkewitz
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-08       Impact factor: 15.336

3.  Dispersion-Energy-Driven Wagner-Meerwein Rearrangements in Oligosilanes.

Authors:  Lena Albers; Saskia Rathjen; Judith Baumgartner; Christoph Marschner; Thomas Müller
Journal:  J Am Chem Soc       Date:  2016-05-19       Impact factor: 15.419

4.  Indirect and Direct Grafting of Transition Metals to Siliconoids.

Authors:  Nadine E Poitiers; Luisa Giarrana; Kinga I Leszczyńska; Volker Huch; Michael Zimmer; David Scheschkewitz
Journal:  Angew Chem Int Ed Engl       Date:  2020-03-20       Impact factor: 15.336

5.  Site-selective functionalization of Si6R6 siliconoids.

Authors:  Yannic Heider; Nadine E Poitiers; Philipp Willmes; Kinga I Leszczyńska; Volker Huch; David Scheschkewitz
Journal:  Chem Sci       Date:  2019-03-14       Impact factor: 9.825

6.  β-Amino- and Alkoxy-Substituted Disilanides.

Authors:  Istvan Balatoni; Johann Hlina; Rainer Zitz; Alexander Pöcheim; Judith Baumgartner; Christoph Marschner
Journal:  Molecules       Date:  2019-10-23       Impact factor: 4.411
  6 in total

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