Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Regio- and enantioselective aminofluorination of alkenes.

Literature DB >> 23362120

Regio- and enantioselective aminofluorination of alkenes.

Wangqing Kong¹, Pascal Feige, Teresa de Haro, Cristina Nevado.

Abstract

Enantio- and regioselective: The intramolecular enantioselective aminofluorination of unactivated olefins was achieved by using a chiral iodo(III) difluoride salt. A highly regioselective aminofluorination of styrenes to access 2-fluoro-2-phenylethanamines was also developed.

Entities: Chemical

Mesh：

Substances：

Year: 2013 PMID： 23362120 DOI： 10.1002/anie.201208471

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

Keyword Cloud
Cited

25 in total

1. Catalytic, Enantioselective 1,2-Difluorination of Cinnamamides.

Authors: Moriana K Haj; Steven M Banik; Eric N Jacobsen
Journal: Org Lett Date: 2019-04-09 Impact factor: 6.005

2. Enantioselective, Catalytic Fluorolactonization Reactions with a Nucleophilic Fluoride Source.

Authors: Eric M Woerly; Steven M Banik; Eric N Jacobsen
Journal: J Am Chem Soc Date: 2016-10-13 Impact factor: 15.419

3. Enantioselective Synthesis of Fluoro-Dihydroquinazolones and -Benzooxazinones by Fluorination-Initiated Asymmetric Cyclization Reactions.

Authors: Kenichi Hiramatsu; Takashi Honjo; Vivek Rauniyar; F Dean Toste
Journal: ACS Catal Date: 2015-12-04 Impact factor: 13.084

4. A 5 + 1 Protic Acid Assisted Aza-Pummerer Approach for Synthesis of 4-Chloropiperidines from Homoallylic Amines.

Authors: Rene Ebule; Sagar Mudshinge; Michael H Nantz; Mark S Mashuta; Gerald B Hammond; Bo Xu
Journal: J Org Chem Date: 2019-02-27 Impact factor: 4.354

5. Mechanism and Origins of Chemo- and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of β-Substituted Styrenes.

Authors: Biying Zhou; Moriana K Haj; Eric N Jacobsen; K N Houk; Xiao-Song Xue
Journal: J Am Chem Soc Date: 2018-11-05 Impact factor: 15.419

Regio- and enantioselective aminofluorination of alkenes.

1. Catalytic, Enantioselective 1,2-Difluorination of Cinnamamides.

2. Enantioselective, Catalytic Fluorolactonization Reactions with a Nucleophilic Fluoride Source.

3. Enantioselective Synthesis of Fluoro-Dihydroquinazolones and -Benzooxazinones by Fluorination-Initiated Asymmetric Cyclization Reactions.

4. A 5 + 1 Protic Acid Assisted Aza-Pummerer Approach for Synthesis of 4-Chloropiperidines from Homoallylic Amines.

5. Mechanism and Origins of Chemo- and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of β-Substituted Styrenes.

6. Catalytic Diastereo- and Enantioselective Fluoroamination of Alkenes.

7. Vanadium-Catalyzed C(sp³)-H Fluorination Reactions.

8. Enantioselective Aryl-Iodide-Catalyzed Wagner-Meerwein Rearrangements.

9. Mild silver-mediated geminal difluorination of styrenes using an air- and moisture-stable fluoroiodane reagent.

10. Palladium-catalyzed enantioselective 1,1-fluoroarylation of aminoalkenes.