Literature DB >> 23360983

Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis.

Peter Bellham1, Michael S Hill, Gabriele Kociok-Köhn, David J Liptrot.   

Abstract

Heavier group 2 (Mg, Ca) bis(trimethylsilyl)amides are catalysts for the formation of unsymmetrical diaminoboranes, [(R(2)N)BH(NR'(2))], by dehydrocoupling of amine boranes and protic amines; a process which is proposed to occur by a sequential metal-centred elimination-insertion-elimination mechanism.

Entities:  

Year:  2013        PMID： 23360983     DOI： 10.1039/c3cc39072a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials.

Authors:  Erin M Leitao; Titel Jurca; Ian Manners
Journal:  Nat Chem       Date:  2013-10       Impact factor: 24.427

2.  Effect of the phosphine steric and electronic profile on the Rh-promoted dehydrocoupling of phosphine-boranes.

Authors:  Thomas N Hooper; Miguel A Huertos; Titel Jurca; Sebastian D Pike; Andrew S Weller; Ian Manners
Journal:  Inorg Chem       Date:  2014-03-11       Impact factor: 5.165

3.  A Highly Active Bidentate Magnesium Catalyst for Amine-Borane Dehydrocoupling: Kinetic and Mechanistic Studies.

Authors:  Alexander C A Ried; Laurence J Taylor; Ana M Geer; Huw E L Williams; William Lewis; Alexander J Blake; Deborah L Kays
Journal:  Chemistry       Date:  2019-04-25       Impact factor: 5.236
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.