| Literature DB >> 23360358 |
Fabian Bebensee1, Christian Bombis, Sundar-Raja Vadapoo, Jacob R Cramer, Flemming Besenbacher, Kurt V Gothelf, Trolle R Linderoth.
Abstract
Using scanning tunneling microscopy, we demonstrate that the 1,3-dipolar cycloaddition between a terminal alkyne and an azide can be performed under solvent-free ultrahigh vacuum conditions with reactants adsorbed on a Cu(111) surface. XPS shows significant degradation of the azide upon adsorption, which is found to be the limiting factor for the reaction.Entities:
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Year: 2013 PMID: 23360358 DOI: 10.1021/ja312303a
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419