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Literature DB >> 23355424

Replacing phosphorus with sulfur for the efficient hydrogenation of esters.

Denis Spasyuk¹, Samantha Smith, Dmitry G Gusev.

Abstract

Catalyst tune-up: A readily available, air-stable amino-sulfide catalyst, [RuCl(2)(PPh(3)){HN(C(2)H(4)SEt)(2)}], has been developed. This complex displays outstanding efficiency for the hydrogenation of a broad range of substrates with C=X bonds (esters, ketones, imines), as well as for the acceptorless dehydrogenative coupling of ethanol to ethyl acetate.

Entities: Chemical

Year: 2013 PMID： 23355424 DOI： 10.1002/anie.201209218

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

13 in total

Review 1. Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

Authors: Aaron M Appel; John E Bercaw; Andrew B Bocarsly; Holger Dobbek; Daniel L DuBois; Michel Dupuis; James G Ferry; Etsuko Fujita; Russ Hille; Paul J A Kenis; Cheryl A Kerfeld; Robert H Morris; Charles H F Peden; Archie R Portis; Stephen W Ragsdale; Thomas B Rauchfuss; Joost N H Reek; Lance C Seefeldt; Rudolf K Thauer; Grover L Waldrop
Journal: Chem Rev Date: 2013-06-14 Impact factor: 60.622

2. Basic Promotors Impact Thermodynamics and Catalyst Speciation in Homogeneous Carbonyl Hydrogenation.

Authors: Wenjun Yang; Tejas Y Kalavalapalli; Annika M Krieger; Taras A Khvorost; Ivan Yu Chernyshov; Manuela Weber; Evgeny A Uslamin; Evgeny A Pidko; Georgy A Filonenko
Journal: J Am Chem Soc Date: 2022-04-27 Impact factor: 16.383

3. CH₂ Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

Authors: Xiaolong Fang; Mingjun Sun; Jianwei Zheng; Bin Li; Linmin Ye; Xiaoping Wang; Zexing Cao; Hongping Zhu; Youzhu Yuan
Journal: Sci Rep Date: 2017-06-21 Impact factor: 4.379

4. Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters.

Authors: Robbert van Putten; Evgeny A Uslamin; Marcel Garbe; Chong Liu; Angela Gonzalez-de-Castro; Martin Lutz; Kathrin Junge; Emiel J M Hensen; Matthias Beller; Laurent Lefort; Evgeny A Pidko
Journal: Angew Chem Int Ed Engl Date: 2017-04-21 Impact factor: 15.336

Replacing phosphorus with sulfur for the efficient hydrogenation of esters.

Review 1. Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

2. Basic Promotors Impact Thermodynamics and Catalyst Speciation in Homogeneous Carbonyl Hydrogenation.

3. CH₂ Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

4. Non-Pincer-Type Manganese Complexes as Efficient Catalysts for the Hydrogenation of Esters.

5. Iridium-catalyzed asymmetric hydrogenation of racemic α-substituted lactones to chiral diols.

6. Synthesis of novel chemicals from cardanol as a product of cashew nutshell processing.

7. Hydrogenation of Polyesters to Polyether Polyols.

Review 8. Ester Hydrogenation with Bifunctional Metal-NHC Catalysts: Recent Advances.

9. From racemic alcohols to enantiopure amines: Ru-catalyzed diastereoselective amination.

10. Preparation of a Series of Supported Nonsymmetrical PNP-Pincer Ligands and the Application in Ester Hydrogenation.