| Literature DB >> 23350834 |
Christine M Beavers1, Andrey V Prosvirin, Andrey V Prosverin, John D Cashion, Kim R Dunbar, Anne F Richards.
Abstract
The reaction of 2-pyridylphosphonic acid (LH(2)) with iron(II) perchlorate and iron(III) nitrate afforded an interconnected, double-layered, cationic iron cage, [{Fe(36)L(44)(H(2)O)(48)}](20+) (1a), the largest interconnected, polynuclear ferric cage reported to date. Magnetic studies on 1a revealed antiferromagnetic coupling between the spins on adjacent Fe(III) ions.Entities:
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Year: 2013 PMID： 23350834 DOI： 10.1021/ic3020145
Source DB: PubMed Journal: Inorg Chem ISSN： 0020-1669 Impact factor: 5.165