| Literature DB >> 23350620 |
Valentín Hornillos1, Manuel Pérez, Martín Fañanás-Mastral, Ben L Feringa.
Abstract
A Cu(I)-phosphoramidite-based catalytic system that allows asymmetric allyl-allyl cross-coupling with high enantioselectivity is reported. This transformation tolerates a large variety of functionalized substrates. The versatility of this new reaction is illustrated in the catalytic asymmetric synthesis of the Martinelline alkaloids chromene derivative core.Entities:
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Year: 2013 PMID： 23350620 DOI： 10.1021/ja312487r
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419