Literature DB >> 23347358

Cooperative supramolecular polymerization driven by metallophilic Pd···Pd interactions.

María José Mayoral1, Christina Rest, Vladimir Stepanenko, Jennifer Schellheimer, Rodrigo Q Albuquerque, Gustavo Fernández.   

Abstract

A new oligophenyleneethynylene (OPE)-based Pd(II) pyridyl complex has been synthesized, and its self-assembly has been investigated in solution, in the bulk state, and on surfaces. Detailed analysis of concentration- and temperature-dependent UV-vis studies in methylcyclohexane supported by DFT calculations demonstrate for the first time that cooperative supramolecular polymerization processes can be driven by metallophilic interactions.

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Year:  2013        PMID： 23347358     DOI： 10.1021/ja312628g

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

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2.  Influence of metal coordination and light irradiation on hierarchical self-assembly processes.

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5.  Mechanistic Insights into Statistical Co-Assembly of Metal Complexes.

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Journal:  ChemistryOpen       Date:  2019-04-02       Impact factor: 2.911

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10.  Thermodynamic insights into the entropically driven self-assembly of amphiphilic dyes in water.

Authors:  Pradeep P N Syamala; Bartolome Soberats; Daniel Görl; Stephan Gekle; Frank Würthner
Journal:  Chem Sci       Date:  2019-08-20       Impact factor: 9.825
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