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Literature DB >> 23345141

Solvent-induced delamination of a multifunctional two dimensional coordination polymer.

Almudena Gallego¹, Cristina Hermosa, Oscar Castillo, Isadora Berlanga, Carlos J Gómez-García, Eva Mateo-Martí, José I Martínez, Fernando Flores, Cristina Gómez-Navarro, Julio Gómez-Herrero, Salome Delgado, Félix Zamora.

Abstract

A coordination polymer is fully exfoliated by solvent-assisted interaction only. The soft-delamination process results from the structure of the starting material, which shows a layered structure with weak layer-to-layer interactions and cavities with the ability to locate several solvents in an unselective way. These results represent a significant step forward towards the production of structurally designed one-molecule thick 2D materials with tailored physico-chemical properties.

Entities: Chemical

Year: 2013 PMID： 23345141 DOI： 10.1002/adma.201204676

Source DB: PubMed Journal: Adv Mater ISSN： 0935-9648 Impact factor: 30.849

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Cited

11 in total

1. Gram-scale synthesis of two-dimensional polymer crystals and their structure analysis by X-ray diffraction.

Authors: Max J Kory; Michael Wörle; Thomas Weber; Payam Payamyar; Stan W van de Poll; Julia Dshemuchadse; Nils Trapp; A Dieter Schlüter
Journal: Nat Chem Date: 2014-07-27 Impact factor: 24.427

2. A nanoporous two-dimensional polymer by single-crystal-to-single-crystal photopolymerization.

Authors: Patrick Kissel; Daniel J Murray; William J Wulftange; Vincent J Catalano; Benjamin T King
Journal: Nat Chem Date: 2014-07-27 Impact factor: 24.427

3. Non-enzymatic electrochemical hydrogen peroxide sensing using a nanocomposite prepared from silver nanoparticles and copper (II)-porphyrin derived metal-organic framework nanosheets.

Authors: Junping Ma; Wushuang Bai; Jianbin Zheng
Journal: Mikrochim Acta Date: 2019-06-27 Impact factor: 5.833

4. Mechanical and optical properties of ultralarge flakes of a metal-organic framework with molecular thickness.

Authors: Cristina Hermosa; Benjamin R Horrocks; José I Martínez; Fabiola Liscio; Julio Gómez-Herrero; Félix Zamora
Journal: Chem Sci Date: 2015-02-16 Impact factor: 9.825

5. Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [Fe^III(acac₂-trien)]⁺ and [Fe^III(sal₂-trien)]⁺ molecules.

Authors: Alexandre Abhervé; Samuel Mañas-Valero; Miguel Clemente-León; Eugenio Coronado
Journal: Chem Sci Date: 2015-05-26 Impact factor: 9.825

Solvent-induced delamination of a multifunctional two dimensional coordination polymer.

1. Gram-scale synthesis of two-dimensional polymer crystals and their structure analysis by X-ray diffraction.

2. A nanoporous two-dimensional polymer by single-crystal-to-single-crystal photopolymerization.

3. Non-enzymatic electrochemical hydrogen peroxide sensing using a nanocomposite prepared from silver nanoparticles and copper (II)-porphyrin derived metal-organic framework nanosheets.

4. Mechanical and optical properties of ultralarge flakes of a metal-organic framework with molecular thickness.

5. Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [Fe^III(acac₂-trien)]⁺ and [Fe^III(sal₂-trien)]⁺ molecules.

6. GO-guided direct growth of highly oriented metal-organic framework nanosheet membranes for H₂/CO₂ separation.

7. Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework.

8. Single-Layered Hybrid Materials Based on 1D Associated Metalorganic Nanoribbons for Controlled Release of Pheromones.

9. Ultrasonic Exfoliation of Hydrophobic and Hydrophilic Metal-Organic Frameworks To Form Nanosheets.

10. Ultrasound-assisted exfoliation of a layered 2D coordination polymer with HER electrocatalytic activity.