| Literature DB >> 23338527 |
George E Salnikov1, Alexander M Genaev, Vladimir A Bushmelev, Vyacheslav G Shubin.
Abstract
Degenerate 1,2-shift of methylethynyl group in long-lived 9,10-dimethyl-9-methylethynyl-phenanthrenium ion has been detected by NMR. This is the first example of ethynyl migration in a long-lived carbocation.Entities:
Year: 2013 PMID： 23338527 DOI： 10.1039/c2ob27208c
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876