Literature DB >> 23334172

A face-capped [Fe4L4]8+ spin crossover tetrahedral cage.

Alan Ferguson1, Marie A Squire, Diana Siretanu, Dmitri Mitcov, Corine Mathonière, Rodolphe Clérac, Paul E Kruger.   

Abstract

Reported here is a face-capped Fe(ii) molecular tetrahedron, [Fe(4)L(4)](BF(4))(8), . Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm displays thermally driven SCO behaviour in the solid state and in dilute acetone solution centred around 284-288 K.

Entities:  

Year:  2013        PMID: 23334172     DOI: 10.1039/c3cc00012e

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Subcomponent Exchange Transforms an FeII4L4 Cage from High- to Low-Spin, Switching Guest Release in a Two-Cage System.

Authors:  Anna J McConnell; Catherine M Aitchison; Angela B Grommet; Jonathan R Nitschke
Journal:  J Am Chem Soc       Date:  2017-04-26       Impact factor: 15.419

2.  Reversible quantitative guest sensing via spin crossover of an iron(ii) triazole.

Authors:  Reece G Miller; Sally Brooker
Journal:  Chem Sci       Date:  2016-02-09       Impact factor: 9.825

  2 in total

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