Literature DB >> 23331076

Molecular iodine catalyzed cross-dehydrogenative coupling reaction between two sp3 C-H bonds using hydrogen peroxide.

Tomoya Nobuta1, Norihiro Tada, Akitoshi Fujiya, Atsumasa Kariya, Tsuyoshi Miura, Akichika Itoh.   

Abstract

A useful method for molecular iodine catalyzed oxidative C-C bond formation between tertiary amines and a carbon nucleophile using hydrogen peroxide as the terminal oxidant is reported. This is the first report of a molecular iodine catalyzed cross-dehydrogenative coupling (CDC) reaction between two sp(3) C-H bonds.

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Year:  2013        PMID： 23331076     DOI： 10.1021/ol303389t

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  6 in total

1.  Metal-free C(sp(3))-H functionalization: oxidative carbo-oxygenation of α-diazo carbonyls via radical dediazotization.

Authors:  Nan-Nan Wang; Wen-Juan Hao; Tian-Shu Zhang; Guigen Li; Ya-Nan Wu; Shu-Jiang Tu; Bo Jiang
Journal:  Chem Commun (Camb)       Date:  2016-03-21       Impact factor: 6.222

2.  I2-catalyzed intramolecular oxidative amination of C(sp3)-H bond: efficient access to 3-acylimidazo[1,2-a]pyridines under neat condition.

Authors:  Lilan Huang; Wenqing Yin; Jian Wang; Chunfang Gan; Yanmin Huang; Chusheng Huang; Yimiao He
Journal:  RSC Adv       Date:  2019-01-18       Impact factor: 4.036

3.  Dual C-H functionalization of N-aryl amines: synthesis of polycyclic amines via an oxidative Povarov approach.

Authors:  Chang Min; Abbas Sanchawala; Daniel Seidel
Journal:  Org Lett       Date:  2014-05-01       Impact factor: 6.005

4.  The redox-Mannich reaction.

Authors:  Weijie Chen; Daniel Seidel
Journal:  Org Lett       Date:  2014-05-23       Impact factor: 6.005

5.  One-pot functionalisation of N-substituted tetrahydroisoquinolines by photooxidation and tunable organometallic trapping of iminium intermediates.

Authors:  Joshua P Barham; Matthew P John; John A Murphy
Journal:  Beilstein J Org Chem       Date:  2014-12-12       Impact factor: 2.883

6.  Toward Rational Understandings of α-C-H Functionalization: Energetic Studies of Representative Tertiary Amines.

Authors:  Wenzhi Luo; Jin-Dong Yang; Jin-Pei Cheng
Journal:  iScience       Date:  2020-01-21
  6 in total

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