| Literature DB >> 23327674 |
Marion C Schäfer1, Svilen Bobev.
Abstract
For a very long time, Ba(16)Ga(32)Sn(104) has been the sole representative of tin clathrates with the type II structure. Herein, we present several new members of this structural family: Cs(8)Ba(16)Ga(39.7(3))Sn(96.3(3)), Rb(9.9(5))Ba(13.3(2))Ga(36.4(3))Sn(99.6(3)), and K(2.0(4))Ba(14.0(4))Ga(30.4(2))Sn(105.6(4)). The successful synthesis of these novel compounds was facilitated through the use of alkali and alkaline-earth metals, which selectively fill the available cages.Entities:
Year: 2013 PMID： 23327674 DOI： 10.1021/ja3112934
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419