Literature DB >> 23323646

2-Pyrrolyloximes in high-nuclearity transition-metal cluster chemistry: Fe10 and Fe12.

Evangelia S Koumousi1, Anastasia Routzomani, Tu N Nguyen, Dimosthenis P Giannopoulos, Catherine P Raptopoulou, Vassilis Psycharis, George Christou, Theocharis C Stamatatos.   

Abstract

The employment of 2-pyrrolyloximes in high-nuclearity transition-metal cluster chemistry has provided access to unprecedented decanuclear and dodecanuclear Fe(III) cagelike clusters bearing the anion of pyrrole-2-carboxaldehyde oxime (praoH(2)), the simplest member of this new family of ligands; the identity of the products depends on the nature of the counteranion present in the starting materials.

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Year:  2013        PMID: 23323646     DOI: 10.1021/ic3023908

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  A high-nuclearity complex containing a decanuclear iron(iii)/oxo cage in a football-like structure and rare (R-/S)-hemiacetalate ligands in a butterfly-like format.

Authors:  Chunying Zheng; Mingyue Liang; Haofen Sun; Jiping Ma; Xuejun Bi; Yang Zhao; Weiqiang Tan; Hui Li
Journal:  RSC Adv       Date:  2019-12-04       Impact factor: 4.036

  1 in total

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