Literature DB >> 23321690

Unbridged Au(II)-Au(II) bonds are theoretically allowed.

Xiao-Gen Xiong1, Pekka Pyykkö.   

Abstract

The bonding in the unbridged closed-shell Au(II)-Au(II) dimers X(4)Au(2)(C(5)H(5)N)(2), X = H, F-I and CF(3), is analyzed and the short Au-Au bonds around 250 pm are reproduced by a novel 6s6p(z)5d(xy) hybridization.

Entities:  

Year:  2013        PMID： 23321690     DOI： 10.1039/c2cc37875b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Cupriphication of gold to sensitize d10-d10 metal-metal bonds and near-unity phosphorescence quantum yields.

Authors:  Rossana Galassi; Mukunda M Ghimire; Brooke M Otten; Simone Ricci; Roy N McDougald; Ruaa M Almotawa; Dieaa Alhmoud; Joshua F Ivy; Abdel-Monem M Rawashdeh; Vladimir N Nesterov; Eric W Reinheimer; Lee M Daniels; Alfredo Burini; Mohammad A Omary
Journal:  Proc Natl Acad Sci U S A       Date:  2017-06-14       Impact factor: 11.205

2.  Dinuclear Au(I), Au(II) and Au(III) Complexes with (CF2 )n Chains: Insights into The Role of Aurophilic Interactions in the Au(I) Oxidation.

Authors:  Alejandro Portugués; Delia Bautista; Juan Gil-Rubio
Journal:  Chemistry       Date:  2021-09-29       Impact factor: 5.020

3.  An element through the looking glass: exploring the Au-C, Au-H and Au-O energy landscape.

Authors:  Dragoş-Adrian Roşca; Joseph A Wright; Manfred Bochmann
Journal:  Dalton Trans       Date:  2015-11-20       Impact factor: 4.390

Review 4.  Excimer and Exciplex Formation in Gold(I) Complexes Preconditioned by Aurophilic Interactions.

Authors:  Hubert Schmidbaur; Helgard G Raubenheimer
Journal:  Angew Chem Int Ed Engl       Date:  2020-06-08       Impact factor: 16.823
  4 in total

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