Literature DB >> 23295954

Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation.

Benito Alcaide1, Pedro Almendros, Sara Cembellín, Teresa Martínez del Campo, Israel Fernández.   

Abstract

The divergent gold-catalysed reactivity (C(sp(2))-H versus C(sp(3))-H) of aryloxy-tethered allenes has been uncovered.

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Year:  2013        PMID: 23295954     DOI: 10.1039/c2cc37872h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Accessing alternative reaction pathways of the intermolecular condensation between homo-propargyl alcohols and terminal alkynes through divergent gold catalysis.

Authors:  Courtney A Smith; Stephen E Motika; Lukasz Wojtas; Xiaodong Shi
Journal:  Chem Commun (Camb)       Date:  2017-02-16       Impact factor: 6.222

2.  Gold-catalyzed oxycyclization of allenic carbamates: expeditious synthesis of 1,3-oxazin-2-ones.

Authors:  Benito Alcaide; Pedro Almendros; M Teresa Quirós; Israel Fernández
Journal:  Beilstein J Org Chem       Date:  2013-04-26       Impact factor: 2.883

  2 in total

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