| Literature DB >> 23280412 |
Chang Hoon Lee1, Daniel A Lutterman, Daniel G Nocera.
Abstract
Photolysis of [Ni(II)(μ-Cl)Cl(IPr)](2) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) activates the Ni-Cl bonds to furnish [Ni(I)(μ-Cl)(IPr)](2). Consistent with this photochemistry, a TD-DFT calculation for square planar Ni(ii) centre reveals that light excitation leads to the population of orbitals with σ*(Ni-Cl) character.Entities:
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Year: 2013 PMID： 23280412 DOI： 10.1039/c2dt32885b
Source DB: PubMed Journal: Dalton Trans ISSN： 1477-9226 Impact factor: 4.390