Single molecule bridging between metal electrodes.

Single molecular junctions, in which a single molecule bridges between metal electrodes, have attracted wide attention as novel properties can appear due to their peculiar geometrical and electronic characters. The single molecular junction has also attracted attention due to its potential application in ultrasmall single molecular electronic devices, where single molecules are utilized as active electronic components. Thus, fabrication of single molecular junctions as well as understanding and controlling their properties (e.g. conductance, optical and magnetic properties) have become long-standing goals of scientists and engineers. This review article focuses on the experimental aspects of single molecular junctions, with primary focus on the electron transport mechanism.