Literature DB >> 23255401

Desymmetrization catalyzed by transition-metal complexes: enantioselective formation of silicon-stereogenic silanes.

Li-Wen Xu1.   

Abstract

Prochiral silanes: recent work has demonstrated the powerful potential of enantioselective desymmetrization catalyzed by transition-metal complexes in the stereoselective formation of silicon-stereogenic silanes. These methods offer new possibilities for asymmetric synthesis of any functionalized chiral silanes that possess tetraorganosilicon stereocenters.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 23255401     DOI： 10.1002/anie.201207932

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Nickel(0)-catalyzed divergent reactions of silacyclobutanes with internal alkynes.

Authors:  Xi-Chao Wang; Bo Li; Cheng-Wei Ju; Dongbing Zhao
Journal:  Nat Commun       Date:  2022-06-13       Impact factor: 17.694

2.  Rhodium-catalyzed asymmetric synthesis of silicon-stereogenic silicon-bridged arylpyridinones.

Authors:  Ryo Shintani; Ryo Takano; Kyoko Nozaki
Journal:  Chem Sci       Date:  2015-11-09       Impact factor: 9.825

3.  Asymmetric retro-[1,4]-Brook rearrangement of 3-silyl allyloxysilanes via chirality transfer from silicon to carbon.

Authors:  Ya Wu; Hua Chen; Wenyu Yang; Yu Fan; Lu Gao; Zhishan Su; Changwei Hu; Zhenlei Song
Journal:  RSC Adv       Date:  2019-08-21       Impact factor: 4.036

4.  Organocatalytic Asymmetric Synthesis of Si-Stereogenic Silyl Ethers.

Authors:  Hui Zhou; Jung Tae Han; Nils Nöthling; Monika M Lindner; Judith Jenniches; Clemens Kühn; Nobuya Tsuji; Li Zhang; Benjamin List
Journal:  J Am Chem Soc       Date:  2022-06-01       Impact factor: 16.383
  4 in total

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