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Literature DB >> 23255355

An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites.

Irene Prat¹, Laura Gómez, Mercè Canta, Xavi Ribas, Miquel Costas.

Abstract

Many are called but few are chosen: A nonheme iron complex catalyzes the oxidation of alkyl C-H bonds by using H(2)O(2) as the oxidant, showing an enhanced selectivity for secondary over tertiary C-H bonds (see scheme).

Entities: Chemical

Year: 2012 PMID： 23255355 DOI： 10.1002/chem.201203281

Source DB: PubMed Journal: Chemistry ISSN： 0947-6539 Impact factor: 5.236

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Cited

7 in total

Review 1. Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.

Authors: Giorgio Olivo; Olaf Cussó; Margarida Borrell; Miquel Costas
Journal: J Biol Inorg Chem Date: 2017-01-25 Impact factor: 3.358

2. Metal-Free Preparation of Cycloalkyl Aryl Sulfides via Di-tert-butyl Peroxide-Promoted Oxidative C(sp3)[BOND]H Bond Thiolation of Cycloalkanes.

Authors: Jincan Zhao; Hong Fang; Jianlin Han; Yi Pan; Guigen Li
Journal: Adv Synth Catal Date: 2014-08-10 Impact factor: 5.837

3. Practical and Selective sp³ C-H Bond Chlorination via Aminium Radicals.

Authors: Alastair J McMillan; Martyna Sieńkowska; Piero Di Lorenzo; Gemma K Gransbury; Nicholas F Chilton; Michela Salamone; Alessandro Ruffoni; Massimo Bietti; Daniele Leonori
Journal: Angew Chem Int Ed Engl Date: 2021-02-25 Impact factor: 15.336

4. Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C-H oxidation.

Authors: Federico Frateloreto; Giorgio Capocasa; Giorgio Olivo; Karim Abdel Hady; Carla Sappino; Marika Di Berto Mancini; Stefano Levi Mortera; Osvaldo Lanzalunga; Stefano Di Stefano
Journal: RSC Adv Date: 2020-12-24 Impact factor: 3.361

An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites.

Review 1. Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.

2. Metal-Free Preparation of Cycloalkyl Aryl Sulfides via Di-tert-butyl Peroxide-Promoted Oxidative C(sp3)[BOND]H Bond Thiolation of Cycloalkanes.

3. Practical and Selective sp³ C-H Bond Chlorination via Aminium Radicals.

4. Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C-H oxidation.

5. Carboxylate-assisted C(sp³)-H activation in olefin metathesis-relevant ruthenium complexes.

6. Selective C(sp³ )-H Aerobic Oxidation Enabled by Decatungstate Photocatalysis in Flow.

Review 7. Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration.

An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites.

Review 1. Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.

2. Metal-Free Preparation of Cycloalkyl Aryl Sulfides via Di-tert-butyl Peroxide-Promoted Oxidative C(sp3)[BOND]H Bond Thiolation of Cycloalkanes.

3. Practical and Selective sp3 C-H Bond Chlorination via Aminium Radicals.

4. Increasing the steric hindrance around the catalytic core of a self-assembled imine-based non-heme iron catalyst for C-H oxidation.

5. Carboxylate-assisted C(sp³)-H activation in olefin metathesis-relevant ruthenium complexes.

6. Selective C(sp3 )-H Aerobic Oxidation Enabled by Decatungstate Photocatalysis in Flow.

Review 7. Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration.

3. Practical and Selective sp³ C-H Bond Chlorination via Aminium Radicals.

6. Selective C(sp³ )-H Aerobic Oxidation Enabled by Decatungstate Photocatalysis in Flow.