| Literature DB >> 23247863 |
Hailong Wang1, Dongdong Qi, Zheng Xie, Wei Cao, Kang Wang, Hong Shang, Jianzhuang Jiang.
Abstract
A hexakis[2,3,9,10,16,17,23,24-octa(butyloxy)phthalocyaninato] samarium(III)-cadmium(II) sextuple-decker complex (Pc*)Sm(Pc*)Cd(Pc*)Cd(Pc*)Cd(Pc*)Sm(Pc*) (1) with six phthalocyanine ligands bridged by two samarium(III) and three cadmium(II) ions, representing the largest stacked tetrapyrrole metal molecule in the sandwich series in terms of the tetrapyrrole-deck number, has been synthesized and characterized spectroscopically and electrochemically. Investigation of the nonlinear optical properties reveals the excellent optical limiting property of this compound.Year: 2013 PMID: 23247863 DOI: 10.1039/c2cc38088a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222