Literature DB >> 23237433

Conversion of F-BODIPYs to Cl-BODIPYs: enhancing the reactivity of F-BODIPYs.

Travis Lundrigan1, Alison Thompson.   

Abstract

A new method for the synthesis of Cl-BODIPYs from F-BODIPYs is reported, merely requiring treatment of the F-BODIPY with boron trichloride. Cl-BODIPYs are exploited as synthetic intermediates generated in situ for the overall conversion of F-BODIPYs to O- and C-BODIPYs in high overall yields using a mild one-pot procedure. This route enables F-BODIPYs to be transformed into derivatives that are not accessible via the direct route, as demonstrated via the use of 1,3-propanediol.

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Year:  2012        PMID： 23237433     DOI： 10.1021/jo302277d

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  3 in total

1.  BCl3-Activated Synthesis of COO-BODIPY Laser Dyes: General Scope and High Yields under Mild Conditions.

Authors:  César Ray; Christopher Schad; Florencio Moreno; Beatriz L Maroto; Jorge Bañuelos; Teresa Arbeloa; Inmaculada García-Moreno; Cassie Villafuerte; Gilles Muller; Santiago de la Moya
Journal:  J Org Chem       Date:  2020-03-17       Impact factor: 4.354

2.  Efficient deprotection of F-BODIPY derivatives: removal of BF2 using Brønsted acids.

Authors:  Mingfeng Yu; Joseph K-H Wong; Cyril Tang; Peter Turner; Matthew H Todd; Peter J Rutledge
Journal:  Beilstein J Org Chem       Date:  2015-01-09       Impact factor: 2.883

3.  Stability of a Series of BODIPYs in Acidic Conditions: An Experimental and Computational Study into the Role of the Substituents at Boron.

Authors:  Maodie Wang; M Graça H Vicente; Deanna Mason; Petia Bobadova-Parvanova
Journal:  ACS Omega       Date:  2018-05-21
  3 in total

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