Literature DB >> 23235693

Effect of gas pressure on negative thermal expansion in MOF-5.

Nina Lock1, Mogens Christensen, Cameron J Kepert, Bo B Iversen.   

Abstract

Powder diffraction is used to study thermal expansion properties of MOF-5 at moderate helium gas pressures: 1.7 bar (100-500 K) and 5-150 bar (150-300 K). The framework shows negative thermal expansion (NTE) at all pressures, but vibrational motions causing NTE are damped with increasing pressures, leading to decreased NTE.

Entities:  

Year:  2013        PMID： 23235693     DOI： 10.1039/c2cc37415c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  Controlling Thermal Expansion: A Metal-Organic Frameworks Route.

Authors:  Salvador R G Balestra; Rocio Bueno-Perez; Said Hamad; David Dubbeldam; A Rabdel Ruiz-Salvador; Sofia Calero
Journal:  Chem Mater       Date:  2016-10-25       Impact factor: 9.811

2.  How to get maximum structure information from anisotropic displacement parameters obtained by three-dimensional electron diffraction: an experimental study on metal-organic frameworks.

Authors:  Laura Samperisi; Xiaodong Zou; Zhehao Huang
Journal:  IUCrJ       Date:  2022-06-08       Impact factor: 5.588

3.  Crystallographic studies of gas sorption in metal-organic frameworks.

Authors:  Elliot J Carrington; Iñigo J Vitórica-Yrezábal; Lee Brammer
Journal:  Acta Crystallogr B Struct Sci Cryst Eng Mater       Date:  2014-05-24
  3 in total

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