| Literature DB >> 23229014 |
Jun Hu1, Qingjing Yang, Jianbin Xu, Chao Huang, Baomin Fan, Jun Wang, Chengyuan Lin, Zhaoxiang Bian, Albert S C Chan.
Abstract
Oxabenzonorbornadienes were found to be suitable substrates for asymmetric hydroalkynylation reactions. Catalyzed by the complex of [Ir(COD)Cl](2) and (R)-SYNPHOS, oxabenzonorbornadienes and terminal alkynes could react smoothly to give the alkynylated products in moderate to good yields (up to 93% yield) and enantioselectivities (up to 85% ee).Entities:
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Year: 2012 PMID： 23229014 DOI： 10.1039/c2ob26775f
Source DB: PubMed Journal: Org Biomol Chem ISSN： 1477-0520 Impact factor: 3.876