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Literature DB >> 23205321

Strain-Promoted Crosslinking of PEG-based Hydrogels via Copper-Free Cycloaddition.

Jukuan Zheng¹, Laura A Smith Callahan, Jinkun Hao, Kai Guo, Chrys Wesdemiotis, R A Weiss, Matthew L Becker.

Abstract

The synthesis of a 4-dibenzocyclooctynol (DIBO) functionalized polyethylene glycol (PEG) and fabrication of hydrogels via strain-promoted, metal-free, azide-alkyne cycloaddition is reported. The resulting hydrogel materials provide a versatile alternative in which to encapsulate cells that are sensitive to photochemical or chemical crosslinking mechanisms.

Entities: Chemical Disease Species

Year: 2012 PMID： 23205321 PMCID： PMC3507357 DOI： 10.1021/mz3003775

Source DB: PubMed Journal: ACS Macro Lett Impact factor: 6.903

25 in total

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Review 8. Regenerative biomaterials that "click": simple, aqueous-based protocols for hydrogel synthesis, surface immobilization, and 3D patterning.

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9. Copper-free click chemistry in living animals.

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10. In vivo imaging of Caenorhabditis elegans glycans.

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Review 3. Designing degradable hydrogels for orthogonal control of cell microenvironments.

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4. PEG-Anthracene Hydrogels as an On-Demand Stiffening Matrix To Study Mechanobiology.

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7. Neural stem cell encapsulation and differentiation in strain promoted crosslinked polyethylene glycol-based hydrogels.

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8. Facile Quenching and Spatial Patterning of Cylooctynes via Strain-Promoted Alkyne-Azide Cycloaddition of Inorganic Azides.

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9. Design of Thiol- and Light-sensitive Degradable Hydrogels using Michael-type Addition Reactions.

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10. Facile fabrication of "dual click" one- and two-dimensional orthogonal peptide concentration gradients.

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