| Literature DB >> 23203152 |
Saul H Lapidus1, Jamie L Manson, Hyunsoo Park, Alexander J Clement, Saman Ghannadzadeh, Paul Goddard, Tom Lancaster, Johannes S Möller, Stephen J Blundell, Mark T F Telling, Jinhee Kang, Myung-Hwan Whangbo, John A Schlueter.
Abstract
CuF(2)(H(2)O)(2)(3-chloropyridine) possesses a five-coordinate Cu(2+) center with a slightly distorted trigonal bypyramidal coordination geometry. Strong intermolecular F···H-O hydrogen bonds enable the formation of 2D layers and provide the primary magnetic exchange path that leads to the stabilization of long-range antiferromagnetic (AFM) order below T(N) = 2.1 K.Entities:
Year: 2013 PMID： 23203152 DOI： 10.1039/c2cc37444g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222