Literature DB >> 23198284

Chemoselective nitration of aromatic sulfonamides with tert-butyl nitrite.

Brenden Kilpatrick1, Markus Heller, Steve Arns.   

Abstract

A methodology for the efficient conversion of aromatic sulfonamides into their mono-nitro derivatives using tert-butyl nitrite is reported. The reaction exhibits a high degree of chemoselectivity for sulfonamide functionalized aryl systems, even in the presence of other sensitive or potentially reactive functionalities.

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Year:  2013        PMID: 23198284     DOI: 10.1039/c2cc37481a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  3 in total

1.  Electrochemical Nitration with Nitrite.

Authors:  Stephan P Blum; Christean Nickel; Lukas Schäffer; Tarik Karakaya; Siegfried R Waldvogel
Journal:  ChemSusChem       Date:  2021-10-22       Impact factor: 9.140

2.  Facile access to nitroarenes and nitroheteroarenes using N-nitrosaccharin.

Authors:  Roxan Calvo; Kun Zhang; Alessandro Passera; Dmitry Katayev
Journal:  Nat Commun       Date:  2019-07-30       Impact factor: 14.919

3.  Site-selective and metal-free C-H nitration of biologically relevant N-heterocycles.

Authors:  Junghyea Moon; Hyun Ku Ji; Nayoung Ko; Harin Oh; Min Seo Park; Suho Kim; Prithwish Ghosh; Neeraj Kumar Mishra; In Su Kim
Journal:  Arch Pharm Res       Date:  2021-10-18       Impact factor: 4.946

  3 in total

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