| Literature DB >> 23190753 |
Debabrata Mukherjee1, Nicole L Lampland, KaKing Yan, James F Dunne, Arkady Ellern, Aaron D Sadow.
Abstract
Synthesis and reactivity of monomeric magnesium and zinc silyl compounds To(M)M-Si(SiHMe2)3 and To(M)M-Si(SiMe3)3 are described (To(M) = tris(4,4-dimethyl-2-oxazolinyl)phenylborate). The magnesium compounds react slowly with water and air, while the zinc compounds are inert. With CO2, To(M)Mg-Si(SiHMe2)3 provides To(M)MgO2CSi(SiHMe2)3 through CO2 insertion, whereas To(M)Zn-Si(SiHMe2)3 affords To(M)ZnOCHO.Entities:
Year: 2012 PMID： 23190753 DOI： 10.1039/c2cc36953b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222