Literature DB >> 23181470

Iron-catalyzed dioxygen-driven C-C bond formation: oxidative dearomatization of 2-naphthols with construction of a chiral quaternary stereocenter.

Takuya Oguma1, Tsutomu Katsuki.   

Abstract

Iron(salan) complex 1 was found to catalyze the oxidative dearomatization of 1-substituted 2-naphthols with the formation of an all-carbon quaternary stereocenter in air in the presence of nitroalkanes, to afford the corresponding cyclic enones with high enantioselectivity of 88-96% ee.

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Year:  2012        PMID： 23181470     DOI： 10.1021/ja310203c

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  11 in total

1.  Palladium-Catalyzed Dearomative syn-1,4-Carboamination.

Authors:  Mikiko Okumura; Alexander S Shved; David Sarlah
Journal:  J Am Chem Soc       Date:  2017-12-05       Impact factor: 15.419

2.  Palladium-Catalyzed Dearomative syn-1,4-Diamination.

Authors:  William C Wertjes; Mikiko Okumura; David Sarlah
Journal:  J Am Chem Soc       Date:  2018-12-21       Impact factor: 15.419

3.  Palladium-Catalyzed Dearomative syn-1,4-Carboamination with Grignard Reagents.

Authors:  Conghui Tang; Mikiko Okumura; Yunbo Zhu; Annie R Hooper; Yu Zhou; Yu-Hsuan Lee; David Sarlah
Journal:  Angew Chem Int Ed Engl       Date:  2019-06-24       Impact factor: 15.336

4.  A convergent, modular approach to functionalized 2,1-borazaronaphthalenes from 2-aminostyrenes and potassium organotrifluoroborates.

Authors:  Steven R Wisniewski; Courtney L Guenther; O Andreea Argintaru; Gary A Molander
Journal:  J Org Chem       Date:  2013-12-11       Impact factor: 4.354

5.  Nickel-Catalyzed Dearomative trans-1,2-Carboamination.

Authors:  Lucas W Hernandez; Ulrich Klöckner; Jola Pospech; Lilian Hauss; David Sarlah
Journal:  J Am Chem Soc       Date:  2018-03-23       Impact factor: 15.419

6.  Accessing molecularly complex azaborines: palladium-catalyzed Suzuki-Miyaura cross-couplings of brominated 2,1-borazaronaphthalenes and potassium organotrifluoroborates.

Authors:  Gary A Molander; Steven R Wisniewski
Journal:  J Org Chem       Date:  2014-07-01       Impact factor: 4.354

7.  Accessing 2,1-borazaronaphthols: self-arylation of 1-alkyl-2-aryl-3-bromo-2,1-borazaronaphthalenes.

Authors:  Gary A Molander; Steven R Wisniewski
Journal:  J Org Chem       Date:  2014-08-18       Impact factor: 4.354

8.  Catalytic asymmetric hydroxylative dearomatization of 2-naphthols: synthesis of lacinilene derivatives.

Authors:  Yu Zhang; Yuting Liao; Xiaohua Liu; Xi Xu; Lili Lin; Xiaoming Feng
Journal:  Chem Sci       Date:  2017-07-24       Impact factor: 9.825

9.  Asymmetric Oxidative Coupling of Phenols and Hydroxycarbazoles.

Authors:  Houng Kang; Young Eun Lee; Peddiahgari Vasu Govardhana Reddy; Sangeeta Dey; Scott E Allen; Kyle A Niederer; Paul Sung; Kirsten Hewitt; Carilyn Torruellas; Madison R Herling; Marisa C Kozlowski
Journal:  Org Lett       Date:  2017-10-12       Impact factor: 6.005

10.  Organocatalytic asymmetric chlorinative dearomatization of naphthols.

Authors:  Qin Yin; Shou-Guo Wang; Xiao-Wei Liang; De-Wei Gao; Jun Zheng; Shu-Li You
Journal:  Chem Sci       Date:  2015-04-27       Impact factor: 9.825
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