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Literature DB >> 23165894

A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.

Andrey V Protchenko¹, Andrew D Schwarz, Matthew P Blake, Cameron Jones, Nikolas Kaltsoyannis, Philip Mountford, Simon Aldridge.

Abstract

Si in sight: a one-pot, single-step synthesis of an acyclic silylsilylene, Si{Si(SiMe(3))(3)}{N(SiMe(3))Dipp} (Dipp=2,6-iPr(2)C(6)H(3)), from a silicon(IV) starting material is reported, together with evidence for a mechanism involving alkali metal silylenoid intermediates.

Entities: Chemical Gene

Year: 2012 PMID： 23165894 DOI： 10.1002/anie.201208554

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

8 in total

1. Single-Site and Cooperative Bond Activation Reactions with Ylide-Functionalized Tetrylenes: A Computational Study.

Authors: Henning Steinert; Julian Löffler; Viktoria H Gessner
Journal: Eur J Inorg Chem Date: 2021-10-26 Impact factor: 2.551

2. Synthesis and Reactivity of a Neutral Homocyclic Silylene.

Authors: Jan Keuter; Alexander Hepp; Anja Massolle; Johannes Neugebauer; Christian Mück-Lichtenfeld; Felicitas Lips
Journal: Angew Chem Int Ed Engl Date: 2021-12-14 Impact factor: 16.823

3. A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene).

Authors: Marcel-Philip Luecke; Luisa Giarrana; Arseni Kostenko; Tobias Gensch; Shenglai Yao; Matthias Driess
Journal: Angew Chem Int Ed Engl Date: 2021-11-25 Impact factor: 16.823

4. A vinyl silylsilylene and its activation of strong homo- and heteroatomic bonds.

Authors: Matthew M D Roy; Michael J Ferguson; Robert McDonald; Yuqiao Zhou; Eric Rivard
Journal: Chem Sci Date: 2019-05-24 Impact factor: 9.825

5. Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C-C bond activation.

Authors: Joschua Helmer; Olli J Pakkanen; Chris Gendy; Alexander Hepp; Heikki M Tuononen; Felicitas Lips
Journal: Chem Commun (Camb) Date: 2022-03-10 Impact factor: 6.222

A generic one-pot route to acyclic two-coordinate silylenes from silicon(IV) precursors: synthesis and structural characterization of a silylsilylene.

1. Single-Site and Cooperative Bond Activation Reactions with Ylide-Functionalized Tetrylenes: A Computational Study.

2. Synthesis and Reactivity of a Neutral Homocyclic Silylene.

3. A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene).

4. A vinyl silylsilylene and its activation of strong homo- and heteroatomic bonds.

5. Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C-C bond activation.

6. DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds.

7. Synthesis, Characterization and Reactivity of a σ-Donating Ni⁰ -Stabilized Silyliumylidene Ion.

Review 8. Phosphorus-ylides: powerful substituents for the stabilization of reactive main group compounds.