Literature DB >> 23165639

A homoleptic tetravalent cerium silylamide.

Alan R Crozier1, Andre M Bienfait, Cäcilia Maichle-Mössmer, Karl W Törnroos, Reiner Anwander.   

Abstract

Treatment of Ce[N(SiHMe(2))(2)](3)(thf)(2) with the chlorinating agents PhICl(2), Ph(3)CCl or C(2)Cl(6) gave the homoleptic Ce(IV) silylamide Ce[N(SiHMe(2))(2)](4). When performed in the absence of donating (solvent) molecules, the trivalent cluster Ce(5)[N(SiHMe(2))(2)](8)Cl(7) was isolated.

Entities:  

Year:  2012        PMID： 23165639     DOI： 10.1039/c2cc37404h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

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  5 in total

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