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Literature DB >> 23161665

Catalytic hydrogenation of cyclic carbonates: a practical approach from CO2 and epoxides to methanol and diols.

Zhaobin Han¹, Liangce Rong, Jiang Wu, Lei Zhang, Zheng Wang, Kuiling Ding.

Abstract

Two birds with one stone: the simultaneous production of two important bulk chemicals, methanol and ethylene glycol, from CO(2) and ethylene oxide has been achieved under mild conditions by the highly efficient homogeneous catalytic hydrogenation of ethylene carbonate in the presence of a (PNP)Ru(II) catalyst.

Entities: Chemical

Year: 2012 PMID： 23161665 DOI： 10.1002/anie.201207781

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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Cited

16 in total

1. Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones.

Authors: R Martin Romero; Neethu Thyagarajan; Nora Hellou; Clément Chauvier; Timothé Godou; Lucile Anthore-Dalion; Thibault Cantat
Journal: Chem Commun (Camb) Date: 2022-05-26 Impact factor: 6.065

2. Sorbitol-derived carbon overlayers encapsulated Cu nanoparticles on SiO₂: Stable and efficient for the continuous hydrogenation of ethylene carbonate.

Authors: Tongyang Song; Yuanyuan Qi; Chen Zhao; Peng Wu; Xiaohong Li
Journal: iScience Date: 2022-09-28

3. Effective hydrogenation of carbonates to produce methanol over a ternary Cu/Zn/Al catalyst.

Authors: Jiachen Li; Liguo Wang; Xiang Hui; Chanjuan Zhang; Yan Cao; Shuang Xu; Peng He; Huiquan Li
Journal: RSC Adv Date: 2020-03-31 Impact factor: 4.036

4. Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine-diphosphine ligands.

Authors: Chong Liu; Jian-Hua Xie; Gui-Long Tian; Wei Li; Qi-Lin Zhou
Journal: Chem Sci Date: 2015-03-04 Impact factor: 9.825

5. CH₂ Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

Authors: Xiaolong Fang; Mingjun Sun; Jianwei Zheng; Bin Li; Linmin Ye; Xiaoping Wang; Zexing Cao; Hongping Zhu; Youzhu Yuan
Journal: Sci Rep Date: 2017-06-21 Impact factor: 4.379

Catalytic hydrogenation of cyclic carbonates: a practical approach from CO2 and epoxides to methanol and diols.

1. Silyl formates as hydrosilane surrogates for the transfer hydrosilylation of ketones.

2. Sorbitol-derived carbon overlayers encapsulated Cu nanoparticles on SiO₂: Stable and efficient for the continuous hydrogenation of ethylene carbonate.

3. Effective hydrogenation of carbonates to produce methanol over a ternary Cu/Zn/Al catalyst.

4. Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine-diphosphine ligands.

5. CH₂ Linkage Effects on the Reactivity of Bis(aminophosphine)-Ruthenium Complexes for Selective Hydrogenation of Esters into Alcohols.

6. Bromide promoted hydrogenation of CO₂ to higher alcohols using Ru-Co homogeneous catalyst.

7. Cyclometalated Ruthenium Pincer Complexes as Catalysts for the α-Alkylation of Ketones with Alcohols.

8. Catalytic Hydrogenation of Cyclic Carbonates using Manganese Complexes.

9. Selective catalytic two-step process for ethylene glycol from carbon monoxide.

10. Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups.