| Literature DB >> 23161604 |
Tyler J Carter1, Jeff W Kampf, Nathaniel K Szymczak.
Abstract
Recharging spent BN fuel: {Cr(CO)(3)} mediates the reduction of borazines by hydride and methyl nucleophiles to generate anionic complexes of dearomatized hexamethylborazine. Subsequent quenching leads to the release of a substituted cyclotriborazane, successfully demonstrating the stepwise reduction of a B=N bond.Entities:
Year: 2012 PMID： 23161604 DOI： 10.1002/anie.201206668
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336