Literature DB >> 23160752

Expanding the coordination chemistry of donor-stabilized group-14 metalenes.

Javier A Cabeza1, Pablo García-Álvarez, Diego Polo.   

Abstract

The transformation of an amidinate germylene, equipped with just one accessible lone pair of electrons on the Ge atom, into a bidentate 4-electron donor κ(2)Ge,N-ligand, has been achieved for the first time, opening new doors to the non-carbene-like coordination chemistry of heavier carbene analogues.

Entities:  

Year:  2012        PMID: 23160752     DOI: 10.1039/c2dt32654j

Source DB:  PubMed          Journal:  Dalton Trans        ISSN: 1477-9226            Impact factor:   4.390


  1 in total

1.  Di-μ-oxido-bis-[bis-(diiso-propyl-aceta-midinato)-κN;κ(2) N,N'-germanium(IV)].

Authors:  Ronny Syre; Nancy Frenzel; Cristian G Hrib; Edmund P Burte; Peter G Jones; Frank T Edelmann
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2013-11-30
  1 in total

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