| Literature DB >> 23160013 |
John M Ketcham1, Berenger Biannic, Aaron Aponick.
Abstract
The Au(I)-catalyzed intermolecular hydroalkoxylation of alkynes with allylic alcohols to provide allyl vinyl ethers that subsequently undergo Claisen rearrangement is reported. This new cascade reaction strategy facilitates the direct formation of γ,δ-unsaturated ketones from simple starting materials in a single step.Entities:
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Year: 2012 PMID： 23160013 DOI： 10.1039/c2cc37166a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222