| Literature DB >> 23154932 |
Chenjie Zeng1, Huifeng Qian, Tao Li, Gao Li, Nathaniel L Rosi, Bokwon Yoon, Robert N Barnett, Robert L Whetten, Uzi Landman, Rongchao Jin.
Abstract
A golden opportunity: the total structure of a Au(36)(SR)(24) nanocluster reveals an unexpected face-centered-cubic tetrahedral Au(28) kernel (magenta). The protecting layer exhibits an intriguing combination of binding modes, consisting of four regular arch-like staples and the unprecedented appearance of twelve bridging thiolates (yellow). This unique protecting network and superatom electronic shell structure confer extreme stability and robustness.Entities:
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Year: 2012 PMID: 23154932 DOI: 10.1002/anie.201207098
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336