Literature DB >> 23135873

MFU-4 -- a metal-organic framework for highly effective H(2)/D(2) separation.

Julia Teufel1, Hyunchul Oh, Michael Hirscher, Mohammad Wahiduzzaman, Lyuben Zhechkov, Agnieszka Kuc, Thomas Heine, Dmytro Denysenko, Dirk Volkmer.   

Abstract

The metal-organic framework, MFU-4, possessing small cavities and apertures, is exploited for quantum sieving of hydrogen isotopes. Quantum mechanically, a molecule confined in a small cavity shows an increase in effective size depending on the particle mass, which leads to a faster deuterium adsorption from a H(2)/D(2) isotope mixture.
Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 23135873     DOI： 10.1002/adma.201203383

Source DB:  PubMed          Journal:  Adv Mater        ISSN： 0935-9648            Impact factor:   30.849


  6 in total

1.  B12X11(H2)-: exploring the limits of isotopologue selectivity of hydrogen adsorption.

Authors:  Toshiki Wulf; Jonas Warneke; Thomas Heine
Journal:  RSC Adv       Date:  2021-09-16       Impact factor: 4.036

2.  Efficient hydrogen isotopologues separation through a tunable potential barrier: The case of a C2N membrane.

Authors:  Yuanyuan Qu; Feng Li; Mingwen Zhao
Journal:  Sci Rep       Date:  2017-05-03       Impact factor: 4.379

3.  Systematic Experimental Study on Quantum Sieving of Hydrogen Isotopes in Metal-Amide-Imidazolate Frameworks with narrow 1-D Channels.

Authors:  Suvendu Sekhar Mondal; Alex Kreuzer; Karsten Behrens; Gisela Schütz; Hans-Jürgen Holdt; Michael Hirscher
Journal:  Chemphyschem       Date:  2019-05-02       Impact factor: 3.102

4.  Selectivity for water isotopologues within metal organic nanotubes.

Authors:  Maurice K Payne; Lindsey C Applegate; Priyanka Singh; Ashini S Jayasinghe; George B Crull; Andrea B Grafton; Christopher M Cheatum; Tori Z Forbes
Journal:  RSC Adv       Date:  2021-05-06       Impact factor: 3.361

5.  Isotope-selective pore opening in a flexible metal-organic framework.

Authors:  Linda Bondorf; Jhonatan Luiz Fiorio; Volodymyr Bon; Linda Zhang; Mariia Maliuta; Sebastian Ehrling; Irena Senkovska; Jack D Evans; Jan-Ole Joswig; Stefan Kaskel; Thomas Heine; Michael Hirscher
Journal:  Sci Adv       Date:  2022-04-13       Impact factor: 14.136

6.  Exploiting Dynamic Opening of Apertures in a Partially Fluorinated MOF for Enhancing H2 Desorption Temperature and Isotope Separation.

Authors:  Linda Zhang; Seohyeon Jee; Jaewoo Park; Minji Jung; Dirk Wallacher; Alexandra Franz; Wonjoo Lee; Minyoung Yoon; Kyungmin Choi; Michael Hirscher; Hyunchul Oh
Journal:  J Am Chem Soc       Date:  2019-12-06       Impact factor: 15.419
  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.