Literature DB >> 23132623

Zirconocene dichloride catalyzed hydrodefluorination of C(sp 2)-F bonds.

Shuhui Yow1, Sarah J Gates, Andrew J P White, Mark R Crimmin.   

Abstract

A two-metal job: Four-coordinate aluminum dihydrides such as 1 are reported as terminal reductants for the selective title reaction. The heterobimetallic complex 2 has been isolated and shown to be catalytically competent.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 23132623     DOI： 10.1002/anie.201207036

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  8 in total

1.  Catalyst-Free Hydrodefluorination of Perfluoroarenes with NaBH4.

Authors:  Timothy D Schoch; Mukulesh Mondal; Jimmie D Weaver
Journal:  Org Lett       Date:  2021-02-15       Impact factor: 6.005

2.  Addition of Carbon-Fluorine Bonds to a Mg(I)-Mg(I) Bond: An Equivalent of Grignard Formation in Solution.

Authors:  Clare Bakewell; Andrew J P White; Mark R Crimmin
Journal:  J Am Chem Soc       Date:  2016-09-22       Impact factor: 15.419

3.  Magnesium, zinc, aluminium and gallium hydride complexes of the transition metals.

Authors:  Michael J Butler; Mark R Crimmin
Journal:  Chem Commun (Camb)       Date:  2017-01-24       Impact factor: 6.222

4.  Hydride oxidation from a titanium-aluminum bimetallic complex: insertion, thermal and electrochemical reactivity.

Authors:  Alexandra C Brown; Alison B Altman; Trevor D Lohrey; Stephan Hohloch; John Arnold
Journal:  Chem Sci       Date:  2017-05-31       Impact factor: 9.825

5.  Exploring Equilibria between Aluminium(I) and Aluminium(III): The Formation of Dihydroalanes, Masked Dialumenes and Aluminium(I) Species.

Authors:  Clare Bakewell; Katie Hobson; Claire J Carmalt
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-17       Impact factor: 16.823

6.  Oxidative addition of carbon-fluorine and carbon-oxygen bonds to Al(I).

Authors:  Mark R Crimmin; Michael J Butler; Andrew J P White
Journal:  Chem Commun (Camb)       Date:  2015-09-21       Impact factor: 6.222

7.  Isomerization of Cyclooctadiene to Cyclooctyne with a Zinc/Zirconium Heterobimetallic Complex.

Authors:  Michael J Butler; Andrew J P White; Mark R Crimmin
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-13       Impact factor: 15.336

8.  Catalytic Hydrodefluorination via Oxidative Addition, Ligand Metathesis, and Reductive Elimination at Bi(I)/Bi(III) Centers.

Authors:  Yue Pang; Markus Leutzsch; Nils Nöthling; Felix Katzenburg; Josep Cornella
Journal:  J Am Chem Soc       Date:  2021-08-06       Impact factor: 15.419
  8 in total

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