Literature DB >> 23129209

Cooperative spin transition in a mononuclear manganese(III) complex.

Paulo N Martinho1, Brendan Gildea, Michelle M Harris, Tibebe Lemma, Anil D Naik, Helge Müller-Bunz, Tia E Keyes, Yann Garcia, Grace G Morgan.   

Abstract

Mind the gap: A complete, cooperative spin transition for a mononuclear Mn(III) complex is reported with an 8 K hysteresis window. Raman spectra collected at a single temperature in warming and cooling modes confirm the electronic bistability within the hysteresis loop. The source of the cooperativity is a disconnection in the hydrogen-bonded 1D chains that connect adjacent cations owing to an order-disorder transition in the PF(6)(-) counterion.
Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Year:  2012        PMID： 23129209     DOI： 10.1002/anie.201205573

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  5 in total

1.  Modulation of Mn3+ Spin State by Guest Molecule Inclusion.

Authors:  Irina A Kühne; Kane Esien; Laurence C Gavin; Helge Müller-Bunz; Solveig Felton; Grace G Morgan
Journal:  Molecules       Date:  2020-11-28       Impact factor: 4.411

2.  Domain Wall Dynamics in a Ferroelastic Spin Crossover Complex with Giant Magnetoelectric Coupling.

Authors:  Vibe Boel Jakobsen; Elzbieta Trzop; Emiel Dobbelaar; Laurence C Gavin; Shalinee Chikara; Xiaxin Ding; Minseong Lee; Kane Esien; Helge Müller-Bunz; Solveig Felton; Eric Collet; Michael A Carpenter; Vivien S Zapf; Grace G Morgan
Journal:  J Am Chem Soc       Date:  2021-12-23       Impact factor: 15.419

3.  Homochiral Mn3+ Spin-Crossover Complexes: A Structural and Spectroscopic Study.

Authors:  Irina A Kühne; Andrew Ozarowski; Aizuddin Sultan; Kane Esien; Anthony B Carter; Paul Wix; Aoife Casey; Mooneerah Heerah-Booluck; Tony D Keene; Helge Müller-Bunz; Solveig Felton; Stephen Hill; Grace G Morgan
Journal:  Inorg Chem       Date:  2022-02-17       Impact factor: 5.165

4.  Spin-Crossover and Slow Magnetic Relaxation Behavior in Hexachlororhenate(IV) Salts of Mn(III) Complexes [Mn(5-Hal-sal2323)]2[ReCl6] (Hal = Cl, Br).

Authors:  Aleksandra V Tiunova; Anna V Kazakova; Denis V Korchagin; Gennady V Shilov; Sergey M Aldoshin; Aleksei I Dmitriev; Mikhail V Zhidkov; Konstantin V Zakharov; Eduard B Yagubskii
Journal:  Int J Mol Sci       Date:  2022-09-28       Impact factor: 6.208

5.  Spin state switching in iron coordination compounds.

Authors:  Philipp Gütlich; Ana B Gaspar; Yann Garcia
Journal:  Beilstein J Org Chem       Date:  2013-02-15       Impact factor: 2.883
  5 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.